Secular variations of the upper crust composition: Implication of geochemical data on the Upper Precambrian shales from the Southern Urals western flank and Uchur-Maya region     

A. V. Maslov  V. N. Podkovyrov  Yu. L. Ronkin  M. T. Krupenin  E. Z. Gareev  V. M. Gorozhanin 《Stratigraphy and Geological Correlation》2006,14(2):126-149

In the mid-1980s, it was concluded based on geochemical study that Th, Sc, La concentrations and ratios Th/Sc, La/Sc and Eu/Eu* did not wary significantly in the post-Archean time. It was impossible to judge about compositional variations of upper crust during the Riphean and Vendian, because data of that time characterized a limited number of samples from the post-Archean basins of Australia, New Zealand, and Antarctic. Considered in this work are variations of Eu/Eu*, LREE/HREE, Th/Sc, and La/Sc ratios in Upper Precambrian fine-grained siliciclastic rock of the Southern Urals western flank (Bashkirian meganticlinorium) and Uchur-Maya region (Uchur-Maya plate and Yudoma-Maya belt). As is established, only the Eu anomaly in the studied siliciclastic rocks is practically identical to this parameter of the average post-Archean shale. Three other parameters plot on the Riphean-Vendian variation curves with positive and negative excursions of diverse magnitude, which do not coincide always in time. It is assumed that these excursions likely mark stages of local geodynamic activity, destruction of pre-Riphean cratons, and progressing recycling of sedimentary material during the Riphean.  相似文献   

Sediment-Based Study of the Effects of Decreasing Mine Water Pollutionon a Heavily Modified, Nutrient Enriched Lake     

T. Kauppila 《Journal of Paleolimnology》2006,35(1):25-37

Ni and Cu mining and ore processing in Hitura, Western Finland, have resulted in emissions of metal-rich wastewaters into the nearby Kalajoki River since 1970. The wastewaters are discharged into the river 3 km upstream from the eutrophic Lake Pidisjärvi, which is a widening of the river by the town of Nivala. The water level of the lake was elevated by 1.5 m and the extensive macrophyte stands were cut in 1979, profoundly changing the environmental conditions. The effects of the decreasing metal emissions and nutrient concentrations since 1979 on the now open 3.9 km² lake were studied with paleolimnological techniques. A 2-m sediment core was taken from the lake in February 2004 and analysed for sediment chemistry and diatom assemblages. At the coring site, 13 cm of sediment had been deposited since 1979, on top of a bed of undecomposed macrophyte remains. When the sediment chemistry was compared with records of decreasing metal loading since 1979, no correlation was found because post-depositional mobility and changes in sediment characteristics affect the sediment metal profiles. Thus, the reduced emissions from the mine and the lower lake water phosphorus levels have not caused a corresponding decrease in sediment metal and P concentrations. However, both of these environmental variables accounted for a statistically significant percentage of variation in the sedimentary diatom assemblages in a redundancy analysis constrained to a single variable. This relationship persisted for Ni loading even in a partial analysis, while the importance of nutrients was confirmed by the good correlation between diatom-inferred and measured P concentrations. The results suggest that reductions in metal and nutrient loading have had an effect on the algal assemblages even though the sediment concentrations of Ni, Cu or P have not decreased.  相似文献   

Environmental and health risk assessment in abandoned mining area, Zlata Idka, Slovakia   总被引：1，自引：0，他引：1  

S. Rapant  Z. Dietzová  S. Cicmanová 《Environmental Geology》2006,51(3):387-397

The Zlata Idka village is a typical mountainous settlement. As a consequence of more than 500 years of mining activity, its environment has been extensively affected by pollution from potentially toxic elements. This paper presents the results of an environmental-geochemical and health research in the Zlata Idka village, Slovakia. Geochemical analysis indicates that arsenic (As) and antimony (Sb) are enriched in soils, groundwater, surface water and stream sediments. The average As and Sb contents are 892 mg/kg and 818 mg/kg in soils, 195 mg/kg and 249 mg/kg in stream sediments, 0.028 mg/l and 0.021 mg/l in groundwater and 0.024 mg/l and 0.034 mg/l in surface water. Arsenic and Sb concentrations exceed upper permissible limits in locally grown vegetables. Within the epidemiological research the As and Sb contents in human tissues and fluids have been observed (blood, urine, nails and hair) in approximately one third of the village’s population (120 respondents). The average As and Sb concentrations were 16.3 μg/l and 3.8 μg/l in blood, 15.8 μg/l and 18.8 μg/l in urine, 3,179 μg/kg and 1,140 μg/kg in nails and 379 μg/kg and 357 μg/kg in hair. These concentrations are comparatively much higher than the average population. Health risk calculations for the ingestion of soil, water, and vegetables indicates a very high carcinogenic risk (>1/1,000) for as content in soil and water. The hazard quotient [HQ=average daily dose (ADD)/reference dose (RfD)] calculation method indicates a HQ>1 for groundwater As and Sb concentrations.  相似文献   

广西姑婆山里松花岗岩中闪长质包体的地球化学特征及其成因探讨   总被引：8，自引：0，他引：8  

杨策  朱金初  张佩华  谢才富 《高校地质学报》2006,12(3):310-318

广西姑婆山里松花岗岩中广泛发育有大量的闪长质包体，包体的野外地质特征、显微结构、矿物组合及化学组成等特征显示其岩浆快速结晶成因。它们的主量元素在相关图上呈不同程度的直线变异关系。在微量元素方面，包体和寄主花岗岩都富含大离子亲石元素和高场强元素。用锆石饱和温度和角闪石成分估算了包体和寄主花岗岩结晶的温度和压力表明，它们的结晶温度和压力条件相近，分别在793—824℃和（3．5—5．1）×10^8Pa范围内。岩石学和同位素地球化学特征也表明，里松包体和寄主花岗岩基本同时结晶，但壳幔比例和来源有所不同。这些特征总体上说明了里松闪长质包体可能是两种岩浆混合时不完全消化的产物  相似文献   

浙江洪公铝质A型花岗岩类的岩石地球化学及其构造环境   总被引：8，自引：0，他引：8  

卢成忠  汪庆华  董传万  董学发 《高校地质学报》2006,12(4):500-506

初步研究表明，以往被认为是典型的I型花岗岩质岩石的浙江洪公岩体应为铝质A型花岗岩质岩石。该岩体以高钾为特征，K2O 达5％以上，K2O/ Na2O＞1.2，准铝-过铝质（A/NKC=0.80 ～1.14）；FeO*/MgO比值大（平均14.20）,高于M型、S型和I型花岗岩；富含稀土元素（ΣREE=313.09×10-6～523.73×10-6），具有较高的Ga/Al（′104）值（2.92～4.29）和（Zr+Nb+Ce+Y）元素组合值（551.5′10－6～987.4′10－6），而亏损Ba、Sr、P、Ti等；Nd同位素模式年龄为1.3—1.6Ga，反映洪公岩体主要起源于地壳物质的部分熔融。区域背景、构造被动定位特点和地球化学综合分析表明，洪公岩体形成于拉张的构造环境。  相似文献   

黔西南高砷煤的元素地球化学特征   总被引：1，自引：0，他引：1  

谢宏  聂爱国 《贵州地质》2006,23(2):109-113

通过分析黔西南高砷煤的元素地球化学特征,探索高砷煤中微量元素、稀土元素的地球化学行为,从而揭示了高砷煤的形成机理。分析表明,高砷煤与非高砷煤在微量元素含量方面存在较大差异,金、汞、铊矿石与龙潭煤系中的砷具有同源性,龙潭煤系页岩与峨眉山玄武岩在稀土元素组成上具有继承性。  相似文献   

Nd-Sr Isotopic Geochemistry of the Late Archean-Paleoproterozoic Granitoids in the Lüliang-Wutai Terrain, North China Craton,and Implications for Petrogenesis     

CHEN Bin  LIU Shuwen  WANG Rui  CHEN Zhichao  LIU Chaoqun 《《地质学报》英文版》2006,(6)

  相似文献   

基于MAPGIS建立地球化学图形-数据库   总被引：3，自引：0，他引：3  

和志军  郑镝  杨自安  邹林 《物探与化探》2005,29(1):57-61

将建立地球化学图形-数据库过程分为已建立常规地球化学数据库和未建立常规地球化学数据库,其主要区别是采样点位是否具有地理位置坐标。以未建立常规地球化学数据库的情况为例,介绍了利用MAPGIS软件建立和管理地球化学图形-数据库的思路、过程和方法,并简单介绍了利用建立的图形数据库进行检索和地球化学专题图件制作的方法。  相似文献   

黑龙江省中部森林沼泽区 超低密度深穿透地球化学调查采样介质的确定   总被引：2，自引：0，他引：2  

胡忠贤  杨兆武  程志中  王学求 《物探与化探》2005,29(2):105-107,115

通过对王水溶矿法与四酸溶矿法的对比,元素在泛滥平原A层、B层沉积物及水系沉积物中的分配,以及这3种介质圈定的异常对比等综合因素的研究,确定了泛滥平原A层沉积物是黑龙江省中部森林沼泽区开展超低密度深穿透地球化学调查的有效采样介质。  相似文献   

镉的地球化学研究现状及展望   总被引：13，自引：0，他引：13  

叶霖潘自平  李朝阳刘铁庚 夏斌 《岩石矿物学杂志》2005,24(4):339-348

镉是重金属有毒元素,其环境污染一直是众多学者研究的焦点。近年来研究发现,镉等分散元素并不“分散”,它在特定的条件下会富集,甚至形成独立矿床或矿体,因此有必要对镉等分散元素的地球化学行为进行重新认识和再研究。本文介绍了有关镉的分布和赋存状态的一些研究进展,总结了我国镉矿资源的分布及特点和地球化学研究现状,提出应加强镉的超常富集机制、铅锌矿床表生地球化学过程中镉的释放及其对环境的影响方面的研究。  相似文献